chapter 08 : Raman Effect & Spectroscopic Techniques

Ex8.1 : : Pg: 184

#Stokes and anti stokes wavelength
c = 3e+08     # Speed of light, m/s
Lo = 2537e-010     # Wavelength of the exciting line, metre
Ls = 2683e-010     # Wavelength of stokes line, metre
Lm = (Ls * Lo)/(Ls - Lo)     # Raman shift, per m
print "The Raman shift = %5.3e per cm"% (1/Lm*1e-02) 
Lo1 = 5461e-010     # Wavelength of exciting line for stokes wavelength, metre
Ls = (Lm * Lo1)/(Lm - Lo1)     # Stokes wavelength for the new exciting line, metre
Las = (Lm * Lo1)/(Lm + Lo1)     # Anti-Stokes wavelength for the new exciting line, metre
print "The stokes wavelength for the new exciting line = %4d Angstrom"% (Ls/1e-010) 
print "The anti-stokes wavelength for the new exciting line = %4d Angstrom"% (Las/1e-010) 

The Raman shift = 2.145e+03 per cm
The stokes wavelength for the new exciting line = 6185 Angstrom
The anti-stokes wavelength for the new exciting line = 4888 Angstrom

Ex8.2 : : Pg: 185

#Wavelength of infrared absorption line
L1 = 4554     # wavelength of the stokes line, Angstorm
L2 = 4178     # wavelength of antistokes line, Angstorm
Lm = 2*L1*L2/(L1-L2)     # Wavelength of infrared absorption line, Angstorm
print "The Wavelength of infrared absorption line = %5.3e Angstorm"% Lm  

The Wavelength of infrared absorption line = 1.012e+05 Angstorm